In case you have not yet got into details about SQL Server 2005 and ASP.NET 2.0 MSDN Webcast is a good place to start with. There are two new series that will help you catch up.

Essential ASP.NET for the Web Developer from Fritz Onion
http://www.microsoft.com/events/series/essentialaspnet.mspx

A Primer to Proper SQL Server Development from Kimberly Tripp
http://www.microsoft.com/events/series/msdnsqlserver2005.mspx